Molecular absorption spectra of gallium salts in flame

Infra-red Absorption Spectra of Pyrylium Salts

The infra-red absorption spectra of the unsubstituted pyrylium cation and of 25 di-, tri-, tetraand per&-substituted pyrylium salts (mostly perchlorates) with alkyl and/or phenyl groups are described. Assignments of IR bands are made in correlation with the spectrum of pyridine, and the variation of band position and intensity depending on substitution is discussed. Implications for the assignm...

Comparative sensitivities of flame atomic absorption spectrophotometry (AAS) and molecular absorption spectrophotometry (MAS).

A sensitivity comparison was made between conventional atomic absorption spectrophotometry (AAS) and conventional molecular absorption spectrophotometry (MAS) for the serum trace metals, copper, iron, and zinc. The sensitivity aspect considered was absorbances was obtained for concentrations in the solutions analyzed using unit lightpaths of 1 cm and 10 cm for MAS and AAS, respectively. A disti...

Structure absorption spectra correlation in a series of 2,6-dimethyl-4-arylpyrylium salts.

A combined experimental and theoretical study of the absorption spectra of a group of closely related pyrylium perchlorates 1-11 are presented. Minor changes in the position of the substituents lead to drastic changes in the absorption spectra in this series of compounds. We have attempted to explain the observed changes using the x,y-band notation developed by Balaban and co-workers. Absorptio...

Electronic Spectra of Chevreul’s Salts

Cathodoluminescence spectra of gallium nitride nanorods

Gallium nitride [GaN] nanorods grown on a Si(111) substrate at 720°C via plasma-assisted molecular beam epitaxy were studied by field-emission electron microscopy and cathodoluminescence [CL]. The surface topography and optical properties of the GaN nanorod cluster and single GaN nanorod were measured and discussed. The defect-related CL spectra of GaN nanorods and their dependence on temperatu...